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Polyacrylate (PAE)/nano-silica (SiO2) hybrids were prepared by an in situ sol–gel process of tetraethyl orthosilicate in the presence of PAE toluene solution. The hybrid coatings were fabricated using a PAE/SiO2 suspension by the traditional casting. Their intermolecular interaction and morphology, as well as thermal, mechanical, and optical properties, were investigated using Fourier transform infrared...
Based on the thermodynamic and kinetic analyses, the thermotropic hexagonal columnar liquid crystalline (LC) phase of poly-{2,5-bis[(4-butoxyphenyl)oxycarbonyl]styrene} (PBPCS) at high temperature is self-assembled by driving forces of the conformation entropy and macromolecular interaction, respectively. Because of the strong “coupling effect” between flexible backbone and rigid side chain, the molecular...
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