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The intermolecular electrochemiluminescence resonance energy transfer (ECL‐RET) between luminol and Ru(bpy)32+ was studied extensively to achieve the sensitive bioanalysis owing to the perfect spectral overlap of the donor and acceptor, but it still suffers from the challenging issue of low energy‐transfer efficiency. The intramolecular ECL‐RET towards the novel ECL compound containing the donor of...
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