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The mass analyzed threshold ionization spectra of o-fluorophenol and o-methoxyphenol were recorded via many of their respective vibronic states. The adiabatic ionization energies (IEs) of o-fluorophenol and o-methoxyphenol are determined to be 70,006 and 63,995cm −1 , respectively. Comparing these values with those in the literature, one finds that the IE follows the order: para<ortho<meta...
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