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With the bioinspired design of organic ligands and metallic nodes, novel ultrathin 2D bimetallic metal–organic‐framework nanosheets are successfully synthesized, which can serve as advanced 2D biomimetic nanomaterials to mimic heme proteins.
A facile surfactant‐assisted bottom‐up synthetic method to prepare a series of freestanding ultrathin 2D M‐TCPP (M = Zn, Cu, Cd or Co, TCPP = tetrakis(4‐carboxyphenyl)porphyrin) nanosheets with a thickness of sub‐10 nm is developed. As a proof‐of‐concept application, some of them are successfully used as new platforms for DNA detection. The Cu‐TCPP nanosheet‐based sensor shows excellent fluorescent...
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