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There is an enormous growth of interest in graphene, a two-dimensional carbon nanomaterial, exhibiting excellent conductivity, good mechanical and optical properties with an affordable cost. It was also found out that it can be integrated quite effectively with biocatalysts for fabrication of graphene-based biofuel cells (BFCs), where the biocatalysts are used for turning a chemical energy of substrates/biofuels...
This is the first study showing pH dependence of three distinct redox sites within bilirubin oxidase (BOD) adsorbed on a nanocomposite modified electrode. The 1st redox centre with the highest redox potential E c(1st) =404mV vs. Ag/AgCl (614mV vs. NHE at pH7.0) exhibited pH dependence with a slope -dE c(1st) /dpH=66(±3) mV under a non-turnover process. The 2nd redox centre with a potential...
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