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We report two methods that involve tailoring of the chemical composition of the nematic liquid crystal 4-cyano-4′-pentylbiphenyl to achieve control over the orientational ordering of the liquid crystal on chemically functionalized surfaces. The first method involves the direct addition of 4-cyano-4′-biphenylcarboxylic acid to 4-cyano-4′-pentylbiphenyl. The second method involves exposure of 4-cyano-4′-pentylbiphenyl...
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