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Spectroscopic and structural data of 15 complexes with the general formula of RO(O)CCH 2 Co(CO) 3 PPh 3 indicate a novel coordination mode of the α-ester group to the central cobalt atom, which was found to be crucial in the formation of configurational chirality of the ester carbon atom. Stereoselective self-assembly, elongated ester carbonyl bond lengths, reduced carbonyl...
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