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Crystal structure and oxygen storage properties of A-site ordered BaY1−xPrxMn2O5+δ (x=0, 0.25, 0.5, 0.75 and 1) perovskite-type oxides are reported, showing almost complete and reversible change (Δδ>0.94mol mol−1) occurring between fully reduced BaY1−xPrxMn2O5 and oxidized BaY1−xPrxMn2O6 during reduction in 5vol.%H2 in Ar atmosphere and oxidation in air at 500°C. All reduced compounds, as well...
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