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The propulsion of photocatalytic hydrogen (H2) production is limited by the rational design and regulation of catalysts with precise structures and excellent activities. In this work, the [MoOS3]2− unit is introduced into the CuI clusters to form a series of atomically‐precise MoVI−CuI bimetallic clusters of [Cu6(MoOS3)2(C6H5(CH2)S)2(P(C6H4−R)3)4] ⋅ xCH3CN (R=H, CH3, or F), which show high photocatalytic...
The propulsion of photocatalytic hydrogen (H2) production is limited by the rational design and regulation of catalysts with precise structures and excellent activities. In this work, the [MoOS3]2− unit is introduced into the CuI clusters to form a series of atomically‐precise MoVI−CuI bimetallic clusters of [Cu6(MoOS3)2(C6H5(CH2)S)2(P(C6H4−R)3)4] ⋅ xCH3CN (R=H, CH3, or F), which show high photocatalytic...
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