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The critical temperature dependence on Ga concentration in the inter-metallic pseudo-binary Ca(Al 1−x Ga x )Si system is studied. Non-orthogonal tight binding calculations are reported which show that the main contribution to the density of states at the Fermi level (ρ EF ) comes from the Ca3d-orbitals. ρ EF decreases almost linearly along the series. This does...
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