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The tricyclic BCD substructure of the marine natural product nakadomarin A has been synthesised. The strategy utilised a key carbon–carbon bond‐forming reaction between a furan and an N‐acyliminium ion derived from a secondary thiolactam. In addition, a novel three‐component coupling reaction between a thioamide, an allylic bromide and an isocyanate, leading to the establishment of two new stereogenic...
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