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31P MRSI allows for the non‐invasive mapping of pH and magnesium ion content (Mg) in vivo, by translating the chemical shifts of inorganic phosphate and adenosine‐5′‐triphosphate (ATP) to pH and Mg via suitable calibration equations, such as the modified Henderson–Hasselbalch equation. However, the required constants in these calibration equations are typically only determined for physiological conditions,...
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