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A series of dinuclear metal complexes, [M 2 L](ClO 4 ) 2 (M=Mn 2+ , Ni 2+ , Zn 2+ and Cd 2+ ), of a pendant-arm macrocyclic ligand (H 2 L) have been prepared via the cyclocondensation between sodium 2,6-diformyl-4-chlorophenolate and N-(2-methylenepyridinyl)tris(2-aminoethyl)amine and the subsequent transmetallation with metal perchlorates,...
The reaction between sodium 2,6-diformyl-4-X-phenolates (X=Me, Cl) and N,N-bis(2-aminoethyl)-2-hydroxybenzylamine (ahba) followed by in situ transmetallation of Cd(II)(ClO 4 ) 2 or Fe(III)(ClO 4 ) 3 resulted in the production of a dinuclear Cd(II) pendant-arm macrocyclic complex and a mononuclear Fe(III) macrocyclic complex, respectively. Two complexes as well as the...
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