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The kinetics, product analysis and theoretical studies for selective deprotection of N-arylideneamino pyridone, pyrimidinone and triazinone systems were carried out. Their reactivities were compared with each other and with related compounds previously studied. This reaction represents an efficient, clean and general synthetic procedure for the protection and selective synthesis of potential biologically...
RCM of the appropriate bis-allyloxyacetanilides and bis-o-allyloxyphenoxyacetanilides led to an efficient synthetic approach to the corresponding macrocylic polyoxadiamides with 20- to 32-membered ring sizes in good to excellent yields using Grubbs' catalyst.
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