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The geometry of silatrane HSi(OCH2CH2)3N has been determined by gas electron diffraction, ab initio calculations, and vibrational spectroscopy of crystal. Using the scaled force field from DFT calculations the amplitudes and perpendicular corrections were calculated. It was assumed that the silatrane molecule has C3 symmetry. The following values (rg bond lengths in Å and ∠a bond angles in deg...
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