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Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed...
The reactions of ethanol and ethylene glycol have been studied on Ni/Pt(111) bimetallic surfaces using density functional theory (DFT) and high resolution electron energy loss spectroscopy (HREELS). A linear correlation has been observed between the binding energies of ethanol, ethoxy, and ethylene glycol species and the surface d-band center, with increasing binding energy as the d-band center shifts...
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