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A series of single crystals of quasi-one-dimensional chloro-bridged Ni-Pd mixed-metal MX-chain compounds, Ni 1-x Pd x (chxn) 2 Cl 3 (chxn=1R,2R-diaminocyclohexane) have been obtained by electrochemical oxidation methods. In order to investigate the competition between the electron correlation in the Ni(III) states and the electron-phonon interaction in the...
The IR, XPS and resonance Raman spectra of a series of Ni-Pd mixed-metal MX-chain compounds, Ni 1−x Pd x (chxn) 2 Br 3 have been measured in order to investigate the competition between the electron-correlation in Ni III and the electron-phonon interaction in Pd II –Pd IV states. The splitting of doublet signals of the Pd II –Pd IV...
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