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Density measurements, molar volume data, DTA analyses and XPS results on xFe 2 O 3 ·(100−x)[4Bi 2 O 3 ·PbO] samples are presented in order to point out the effect of Fe 2 O 3 addition to the lead–bismuthate matrix on the local order of this system. Fe 2 O 3 acts as network modifier and determines by progressive addition the increase of...
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