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Electronic structures of transition-metal (M) intercalation compounds M x TiS 2 are studied by means of Ti 2p XAS and 2p core excited resonance photoemission (2p RXPS) spectroscopies. It is found that the charge transfer from M atom as well as from the S atom to Ti atom is playing dominant roles in various spectra of M x TiS 2 . The origin of a sharp photoemission structure...
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