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We have examined alkaline sulfidic (0.5–0.003 M Na 2 S), aqueous solutions of Hg(II)-S complexes (4–370 ppm Hg(II)) by Hg L III edge EXAFS spectroscopy at 296, 348 and 423 K. Data were collected using the ID26 High Brilliance X-ray Spectroscopy beamline at the ESRF. Analysis of these EXAFS spectra shows Hg coordinated by two S atoms at 2.30 Å; multiple scattering analyses reveal a...
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