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Abstract Solvent sublation has been performed on very dilute solutions of one cationic surfactant, hexadecylpyridinium chloride (HPC), and one anionic surfactant, dodecylbenzenesulfonic acid (LBS). Some thermodynamic values were obtained, e.g. molecular areas, A0, which are 50.0 and 47.7 2/molecule, respectively, for HPC and LBS, and free adsorption energies, ��Gads, which are 33.17 and 43.58 kJ mol1,...
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