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Barrier-type, nanocrystalline anodic films have been formed on a ZE41 magnesium alloy under a constant current density of 5mAcm −2 in a glycerol/fluoride electrolyte, containing 5vol.% of added water, at 293K. The films contain magnesium, fluorine and oxygen as the major species, and lower amounts of alloying element species. The films grow at an efficiency of ∼0.8 to 0.9, with a formation...
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