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Biaxially oriented CaF 2 films have been created by first using an oblique incidence vapor flux to deposit CaF 2 onto an amorphous surface to form vertically aligned nanorods which served as seeds to grow a more continuous CaF 2 capping layer under a subsequent normal incidence flux deposition. The entire film possesses a unique {111}〈121〉 biaxial texture as shown by X-ray...
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