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S K-edge surface X-ray absorption fine structure measurements reveal that SO 2 is adsorbed on Pd(111) with the molecular plane normal to the surface, via the S atom and one of the O atoms. This is in clear contrast to the SO 2 /Ni cases where the molecule lies flat on the surfaces. Inequivalent intramolecular S-O bonds are clearly identified with the distances of 1.43 9 for the upright...
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