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Fe–Ni alloys are widely used in engineering today. They are sometimes alloyed with boron. Oxygen is a harmful impurity in Fe–Ni alloys. It may be present in dissolved form or as nonmetallic inclusions. The presence of oxygen in Fe–Ni alloys impairs their performance. Research on the thermodynamics of oxygen solutions in Fe–Ni melts containing boron is of considerable interest in order to improve alloy...
By thermodynamic analysis of oxygen solutions in Fe-Ni-O, Fe-Co-O, and Co-Ni-O melts, the composition of the oxide phase is established for the first time. In addition, the equilibrium oxygen concentrations in these melts are determined over the whole range of alloy compositions. In Fe-Ni-O and Fe-Co-O melts, the oxide phase mainly contains FeO over a relatively broad of alloy compositions. Sharp...
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