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The thermal properties of Li 4/3 Ti 5/3 O 4 and Li 1+x Mn 2 O 4 electrodes were investigated by isothermal micro-calorimetry (IMC). The 150-mAhg −1 capacity of a Li/Li 4/3 Ti 5/3 O 4 half cell was obtained through the voltage plateau that occurs at 1.55V during the phase transition from spinel to rock salt. Extra capacity...
In our efforts to develop low cost high-power Li-ion batteries with excellent safety, as well as long cycle and calendar life, lithium manganese oxide spinel and layered lithium nickel cobalt manganese oxide cathode materials were investigated. Our studies with the graphite/LiPF 6 /spinel cells indicated a very significant degradation of capacity with cycling at 55°C. This degradation was...
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