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Lithium-rich layered oxides always suffer from low initial Coulombic efficiency, poor rate capability and rapid voltage fading. Herein, engineering oxygen vacancies in hierarchically Li1.2Mn0.54Ni0.13Co0.13O2 porous microspheres (L@S) is carried out to suppress the formation of irreversible Li2O during the initial discharge process and improve the Li+ diffusion kinetics and structural stability of...
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