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Ordered dichloro-biphenylene-bridged silsesquioxanes are fabricated by interfacial polymerization at the aqueous/organic phase interface, which involves hydrogen bonding and aromatic π–π stacking interaction, which are responsible for the preferential orientation of the organic bridged units. The high-resolution transmission electronic microscopy images and wide angle X-ray powder diffraction patterns...
The polymerization kinetics of acrylamide was investigated in the system of cetyltrimethyltetrammonium bromide-water micelles. The maximal polymerization rate was found at the second critical micelle concentration. A square-root dependence of the polymerization rates, R p , on the initiator concentrations was obtained. Polymerization in microemulsions was also investigated to establish a...
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