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Sodium and magnesium ionic conduction in complex hydrides as a new category of solid-state fast ionic conductors is presented. We first investigated experimentally the sodium ionic conductivities of the representative Na-based complex hydrides NaBH 4 , NaNH 2 , NaAlH 4 , and Na 3 AlH 6 , all of which have single complex anion [BH 4 ] − , [NH...
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