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Direct coupling of alkanes via C−H activation of terminal methyl groups has acquired tremendous interests both scientifically and technically. Herein we present the results of linear alkane‐coupling at the step edges of Cu surfaces at modulated temperatures. Combining the observations of scanning tunneling microscopy (STM) with density functional theory plus dispersion (DFT‐D) calculations, we elucidate...
On-surface synthesis is the bottom-up construction of covalent bonds between molecular building blocks, which has been greatly developed during the past decade. Dozens of reactions have been successfully realized and scrutinized on various surfaces with the help of surface science techniques combined with theoretical calculations. Functional nanoarchitectures such as one-dimensional nanowires, nanoribbons...
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