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A two-phase (CHCl 3 H 2 O) procedure for the synthesis of halogenated compounds has recently been developed. Such procedure mimics the mode of action of the enzymes haloperoxidases which contain vanadium in their active center. We have investigated the possibility to substitute vanadium with molybdenum. The molybdenum-based reactions show some advantages over the vanadium-based...
In the aqueous phase of a two-phase (H 2 O-CH 2 Cl 2 ) system mimicking the hydrophilic and the hydrophobic portions of vanadium dependent bromoperoxidases, (V-BrPO), a mono peroxovanadium complex, formed in situ by addition of H 2 O 2 to NH 4 VO 3 , oxidizes Br - to a species whose nature is still largely unknown. Such species displays...
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