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Enzymes of the methylerythritol phosphate pathway of isoprenoid biosynthesis are attractive anti‐infective drug targets. The last two enzymes of this pathway, IspG and IspH, are [Fe4S4] proteins that are not produced by humans and catalyze 2 H+/ 2 e− reductions with novel mechanisms. In this Review, we summarize recent advances in structural, mechanistic, and inhibitory studies of these two enzymes...
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