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Rare‐Earth Metals
Article number 2302173 by Ashlee J. Howarth and co‐workers focuses on the design and synthesis of nine new isostructural rare‐earth cluster‐based metal‐organic frameworks (MOFs). The rare‐earth ions used are highlighted on the periodic table in the image. The MOF, named CU‐10 (CU = Concordia University), is comprised of pyrene‐based linkers that when excited with UV‐light can be...
The tetratopic linker, 1,3,6,8‐tetrakis(p‐benzoic acid)pyrene (H4TBAPy) along with rare‐earth (RE) ions is used for the synthesis of 9 isostructures of a metal–organic framework (MOF) with shp topology, named RE‐CU‐10 (RE = Y(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), Yb(III), and Lu(III)). The synthesis of each RE‐CU‐10 analogue requires different reaction conditions to achieve phase...
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