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MIL-45 or K[M 3 (BTC) 3 ].5H 2 O (M=Co, Fe) presents a hybrid 3D open structure based on undulating octahedral chains linked by two different trimesate anions. This compound exhibits ferromagnetic behaviour below 10<space>K for the pure Co phase and 20<space>K for the mixed-metal (Co, Fe) phase.
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