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High resolution electron energy loss spectroscopy (HREELS), temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR) were used to study NO adsorption and the reactivity of COads and NOads molecules on Pd(110) and Pt(100) single crystal surfaces. Compared to the Pt(100)-(1 × 1) surface, the unreconstructed Pt(100)-hex surface is chemically inert toward NO dissociation into...
Statistical lattice models which imitate oscillatory and wave dynamics in the adsorbed layer during of carbon monoxide oxidation over Pt(100) and Pd(110) single crystals differing in the mechanism of autooscillation formation are compared. In the case of platinum, oscillations are due to phase transitions of the catalyst surface structure and surface reconstruction under the action of the reaction...
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