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Thermodynamic analyses of phase changes were carried out for the systems BaS-Ln2S3 with Ln=Pr, Sm, Gd, Tb, Er, and Lu, and the phase diagrams have been experimentally constructed. Formation of the Ba3Ln2S6 sulfides with Ln=Tb through Lu was predicted from the thermodynamic behavior of melts, and the existence of these phases has been experimentally confirmed. Heats of melting were estimated for the...
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