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Stickstoffaktivierung: Obwohl P450‐Enzyme Meister der Aktivierung und Insertion von Sauerstoff in C‐H‐Bindungen sind, wurde bisher nicht erforscht, ob sie dies auch mit Stickstoff vermögen. Für Varianten von Cytochrom P450BM3 wurde nun gezeigt, dass sie intramolekulare C‐H‐Aminierungen in Azidsubstraten katalysieren. Mutationen in zwei hochkonservierten Resten führten zu einer signifikanten Erhöhung...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.