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Cluster-size-dependent binding energy (BE) shifts of Ni 2p 3/2 spectra in Ni clusters with respect to bulk Ni metal have been studied as a function of Ni coverage on clean rutile TiO 2 (001) and TiO 2 (110) surfaces at room temperature. As a common method to distinguish initial and final state contributions to the core-level binding energy shifts in clusters, Auger parameter...
We describe an approach to directly image three-dimensional elemental distributions at the crystal-liquid interface with ~1 A spatial resolution. This method, based on the Fourier synthesis of X-ray standing wave data, is demonstrated by imaging the distribution of Sr 2+ , Zn 2+ and Y 3+ adsorbed to the rutile (110)-water interface with no a priori assumptions...
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