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The (0001) surface of α-Mo 2 C has been studied using low-energy electron diffraction (LEED), X-ray photoelectron spectroscopy and angle-resolved photoelectron spectroscopy. When the ion-bombarded (1keV of Ar + ) surface is annealed at 1600K, a C-rich MoC-like surface is formed. The surface gives a complex LEED pattern composed of (1x1) orthorhombic spots, (2x2)R15 o spots,...
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