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In this work, we synthesized n-octylpyrazinium bromide(G-Br) and n-octylpyrazinium hexafluorophosphate(G-PF6) as model guests and studied their host-guest complexation with 1,4-dimethoxypillar[5]arene(DMP5A). Effect of alkylpyrazinium counterions on the host-guest recognition was investigated. Based on the 1H NOESY spectra, the binding site of DMP5A with G-PF6 is the same as that of DMP5A with G-Br...
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