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Background Numerous studies have investigated the effects of isolated CLA supplementation on glucose homeostasis in humans and rodents. However, both the amount and relative abundance of CLA isomers in supplemental form are not representative of what is consumed from natural sources. No study to date has examined the effects of altered CLA isomer content within a natural food source. Our goal was...
An X-ray crystallographic study on the product of the coupling reaction of 2 and 3, revealed suprisingly that the product was cis-dialdehyde 5, rather than trans-dialdehyde 4. Dialdehyde 5 was employed in the synthesis of a new bis-manganese water-splitting complex, originally formulated as the hydrated derivative of 1. However, the structure of the manganese complex derived from 5 should be revised...
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