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From the perturbation formulas for g factors for an orthorhombically compressed octahedral 3d9 group, g factors, and local structures for the [Cu(en)3]2+ groups in Cu(en)3SO4 and Cu(en)3Cu(CN)3 powders are theoretically investigated. The local structure of Cu2+ in Cu(en)3Cu(CN)3 is evaluated by analyzing the experimental g factors and found to exhibit moderate axial compression ΔZ (≈0.018 Å) and planar...
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