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Solvothermal reaction of 1,3,5-benzenetricarboxylic acid (H3btc) with zinc acetate yielded a compound with chemical formulae (Me2NH2)[Zn(btc)]·H2O·DMA (1) (btc = 1,3,5-benzenetricarboxylate, DMA = N,N-dimethylacetamide). 1 shows a 3D non-interpenetrating rutile topological net, which has 1D channels located Me2NH2 counter anion and guest DMA and H2O molecules. The material has no significant adsorption...
By the reaction of [Ag 3 (dppm) 3 I 2 ]I with (NH 4 ) 2 WS 4 in MeCN/DMF (1:1), a trigonal bipyramid-shaped cluster [Ag 3 I (dppm) 2 WS 4 ] (1) was isolated [dppm=bis (diphenylphosphino) methane]. By the reaction of (NH 4 ) 2 WS 4 with AgSCN and dppm in MeCN/DMF (1:1) in the presence of 1,10-phenathroline,...
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