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ABC‐type triblock copolymers are a rising platform especially for oligonucleotide delivery as they offer an additional functionality besides the anyhow needed functions of shielding and complexation. The authors present a polypept(o)ide‐based triblock copolymer synthesized by amine‐initiated ring‐opening polymerization (ROP) of N‐carboxyanhydrides (NCAs), comprising a shielding block A of polysarcosine...