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Two novel reversible addition–fragmentation chain transfer (RAFT) reagents bearing functional groups, S,S′-bis(9-anthrylmethyl) trithiocarbonate (BATTC) and S,S′-bis(1-naphthylmethyl) trithiocarbonate (BNTTC) were synthesized and used for the RAFT polymerizations of styrene (St). The polymerization results showed that the RAFT polymerizations could be well controlled using BNTTC or BATTC as the RAFT...
A novel benzodithioate compound with a pyrene structure in the R group, pyrenylmethyl benzodithioate (PMB) was synthesized. Using PMB as the chain transfer agent (CTA), the RAFT polymerizations of styrene with AIBN as an initiator were carried out in different reaction conditions. The results indicated that PMB was an effective CTA for the RAFT polymerizations of styrene with the “living”/controlled...
SummaryA novel benzodithioate compound with an anthracene structure (anthracen-9-ylmethyl benzodithioate, AMB) was synthesized. Using AMB as the chain transfer agent, the RAFT polymerizations of styrene with AIBN as an initiator were carried out in difference reaction conditions. The polymerization results showed that AMB was an effective RAFT agent for the RAFT polymerizations of styrene with the...
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