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PolymerisationIn ihrer Zuschrift auf S. 8496 ff. zeigen J. Xu, C. J. Hawker, G. Moad, C. Boyer et al., wie einheitliche Oligomere mithilfe von Photoredoxkatalysatoren modular zugänglich sind.
Uniform synthetic polymers with precisely defined molar mass and monomer sequence (primary structure) have many potential high‐value applications. However, a robust and versatile synthetic strategy for these materials remains one of the great challenges in polymer synthesis. Herein we describe proof‐of‐principle experiments for a modular strategy to produce discrete oligomers by a visible‐light‐mediated...
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