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Microbial poly(β,L‐malic acid) was modified with either L‐leucine ethyl ester (L) or L‐phenylalanine methyl ester (F) to produce amphiphylic copolymers. The degradation of these copolymers in aqueous buffer took place under physiological conditions in a few weeks by hydrolysis of the side chain ester group followed by cleavage of the main chain. Spherical nanoparticles with diameters ranging between...
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