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A novel norbornene monomer bearing a thermally curable benzoxazine group is synthesized and polymerized by ROMP using the Grubbs first‐generation ruthenium catalyst. The of the side‐chain benzoxazine functionalized polyoxanorbornene can be up to 87 000 Da with unimodal molecular‐weight distribution and narrow polydispersity between 1.18 and 1.65. Thermally activated ring‐opening...
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