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We prepared anatase TiO2 films by sol–gel method under three thermal firing conditions to investigate the bipolar resistive switching (BRS) and unipolar resistive switching (URS) in Ag/TiO2/Pt structure. The devices are URS in an air atmosphere at 760Torr, while those in an oxygen ambience at 1Torr show BRS accompanying with forming-free and self-compliance. By examining the X-ray photoelectron spectroscopy...
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