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A novel polymeric carboxylato-bridged praseodymium(III) complex of fumarate, [Pr 2 (fum) 3 (H 2 O) 4 ]·5H 2 O (fum, fumarate dianion) has been synthesized and characterized by single-crystal X-ray diffraction studies, magnetic measurements and thermal studies. Single crystal X-ray structural determination reveals that it is a new porous three dimensional pillared...
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